A number of methods are available for characterization of the structural, physical, and chemical properties of fibres. Various methods are used for fibre identification like microscopic methods, solubility, heating and burning method, density and staining etc. End-use property characterization methods often involve use of laboratory techniques which are adapted to simulate actual conditions of average wear on the textile or that can predict performance in end-use.
A number of methods are available for characterization of the structural, physical, and chemical properties of fibers.
End-use property characterization methods often involve use of laboratory techniques which are adapted to simulate actual conditions of average wear on the textile or that can predict performance in end-use. End-use methods are usually voluntary or mandatory standards developed by test or trade organizations or by government agencies. Organizations involved in standards development for textile end-use include the following:
End user properties characterizations are determined on the following aspects:
Fiber Identification Methods
- Microscopic Identification: Positive identification of many natural fibers is possible using the microscope
- Solubility: The chemical structure of polymers in a fiber determines the fiber's basic solubility characteristics
- Heating and Burning Characteristics: The reaction of fibers to heat from an open flame is a useful guide in identification of fibers.
- Density or Specific Gravity: Fiber density may be used as an aid in fiber identification
- Staining: Fibers have differing dyeing characteristics and affinities dependent on the chemical and morphological structure of the fiber.
Structural, Physical and Chemical Characterization
A number of methods are available for characterization of the structural, physical, and chemical properties of fibers.- Optical and Electron Microscopy: Optical microscopy (OM) has been used for many years as a rel iable method to determine the gross morphology of a fiber in longitudinal as well as cross-sectional views.
- Elemental and End-Group Analysis: The qualitative and quantitative analysis of the chemical elements and groups in a fiber may aid in identification and characterization of a fiber
- Infrared Spectroscopy: Infrared spectroscopy is a valuable tool in determination of functional groups within a fiber
- Ultraviolet-Visible Spectroscopy: The ultraviolet-visible spectra of fibers, dyes, and finishes can provide clues concerning the structure of these materials, as well as show the nature of electronic transitions that occur within the material as light is absorbed at various wavelengths by unsaturated groups giving an
electronically excited molecule. - Nuclear Magnetic Resonance Spectroscopy: Nuclear magnetic resonance (NMR) spectroscopy measures the relative magnitude and direction (moment) of spin orientation of the nucleus of the individual atoms within a polymer from a fiber in solution in a highintensity magnetic field
- X-Ray Diffraction: X-rays diffracted from or reflected off of crystalline or semicrystalline polymeric materials will give patterns related to the crystalline and amorphous areas within a fiber
- Thermal Analysis: Physical and chemical changes in fibers may be investigated by measuring changes in selected properties as small samples of fiber are heated at a steady rate over a given temperature range in an inert atmosphere such as nitrogen.
- Molecular Weight Determination: Molecular weight determination methods provide information concerning the average size and distribution of individual polymer molecules making up a fiber
- Mechanical and Tensile Property Measurements: Mechanical and tensile measurements for fibers include tenacity or tensile strength, elongation at break, recovery from limited elongation, stiffness (relative force required to bend the fiber), and recovery from bending.
- Specific Gravity: The specific gravity of a fiber is a measure of its density in relation to the density of the same volume of water, and provides a method to
relate the mass per unit volume of a given fiber to that of other fibers - Environmental Properties: Environmental properties include those physical properties which relate to the environment in which a fiber is found. Moisture regain, solvent solubility, heat conductivity, the physical effect of heat, and the electrical properties depend on the environmental conditions surrounding
the fiber - Chemical Properties: The chemical properties of fibers include the effects of chemical agents including acids, bases, oxidizing agents, reducing agents, and biological agents such as molds and mildews on the fiber and light- and heatinduced chemical changes within the fiber
End-Use Property Characterization
End-use property characterization methods often involve use of laboratory techniques which are adapted to simulate actual conditions of average wear on the textile or that can predict performance in end-use. End-use methods are usually voluntary or mandatory standards developed by test or trade organizations or by government agencies. Organizations involved in standards development for textile end-use include the following:- American Association of Textile Chemists and Colorists (AATCC)
- American National Standards Institute (ANSI)
- American Society for Testing and Materials (ASTM)
- Consumer Product Safety Commission (CPSC)
- Federal Trade Commission (FTC)
- Society of Dyers and Colorists (SDC)
- International Standards Organization (ISO)
- Characteristics Related to Identity, Aesthetics, and Comfort: Fibers are known by common, generic, and trade names. The Textile Fiber Products Identification Act, administered by the Federal Trade Commission, established generic names for all major classes of fibers based on the structure of the fiber
- Characteristics Related to Durability and Wear: The useful I ife of a fabric depends on a number of factors, including the strength, stretch, recovery, toughness, and abrasion resistance of the fiber and the tearing and bursting resistance of the fabrics made from that fiber
- Physical and Chemical Characteristics and Response of Fiber to Its Environmental Surroundings: The physical and chemical characteristics of a fiber affect a number of important end-use properties:
- Heat (physical and chemical) effect on fibers, including the safe ironing temperature and flammability,
- Wetting of and soil removal from the fiber, including laundering, drycleaning, and fiber dyeability and fastness, and
- Chemical resistance, including resistance to attack by household chemicals and atmospheric gases, particularly in the presence of sunlight.
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